Discovery of huge Raman scattering at atomic point contact

IMAGE: Figure 1 (a) Illustration of the experiment. (b) Scanning electron micrograph of a Ag suggestion (top) and scanning tunneling microscopy image of the Si(111)-7×7 surface area. (c) Atomic point contact Raman…
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Credit: NINS/IMS

Nanofabrication of electronic gadgets has actually reached a single nanometer scale (10-9 m). The quick improvement of nanoscience and nanotechnology now needs atomic-scale optical spectroscopy in order to identify atomistic structures that will impact the residential or commercial properties and functions of the electronic gadgets.

The worldwide group headed by Takashi Kumagai at Institute for Molecular Science found a huge improvement of Raman scattering moderated by a development of an atomic point contact in between a plasmonic silver suggestion and a Si(111)-7×7 rebuilded surface area. This was attained by ways of state-of-the-art low-temperature tip-enhanced Raman spectroscopy which enables to perform atomic-scale vibrational spectroscopy.

The found improvement system of Raman scattering will open the possibility of atomic-scale ultrasensitive vibrational spectroscopy to examine surface area structures of semiconductors. In addition, the established atomic-scale optical microscopy will lead the way for checking out atomic-scale light-matter interactions, causing a brand-new discipline in light science and technology.

Super combination of electronic gadgets has actually gone into a single nanometer scale, requiring analytical approaches that can examine atomic-scale structures and problems in information. The improvement of scanning near-field optical microscopy has actually enabled nanoscale imaging and chemical analyses at the nanoscale. More just recently, the spatial resolution of this strategy was shown to reach the atomic scale. In specific, tip-enhanced Raman spectroscopy has actually drawn increasing attention as ultrasensitive chemical microscopy. However, in order to get a Raman signal from semiconductor surface areas, it was needed to even more boost the level of sensitivity.

The research study group used state-of-the-art low-temperature tip-enhanced Raman spectroscopy, established in cooperation with Fritz-Haber Institute, to get the vibration spectra from a silicon surface area. Tip-boosted Raman spectroscopy uses a strong light-matter interaction in between a product and nanoscale light (localized surface area plasmon resonance) produced at an atomically sharp metal suggestion. The research study group found that an atomic point contact development of a silver suggestion and a rebuilt Si(111)-7×7 surface area results in a huge improvement of Raman scattering. Figure 1a shows the experiment. A sharp silver suggestion produced by concentrated ion beam (figure 1b, top) is approached the silicon surface area (figure 1b, bottom), while keeping an eye on the Raman spectra from the junction. Figure 1c shows the waterfall plot of the gotten Raman spectra, where the horizontal axis the Raman shift, and the color scale the Raman strength. When the suggestion remains in the tunneling program, just the optical phonon mode of the bulk silicon is observed at 520 cm-1. However, when the atomic point contact in between the suggestion and the surface area, the strong Raman scattering from the surface area phonon modes all of a sudden appears. These modes vanish once again when the suggestion is moved far from the surface area and the atomic point contact is broken.

The research study group even more showed that this atomic point contact Raman spectroscopy (APCRS) can solve the atomic-scale structures of the silicon surface area. As displayed in figure 2, the Raman spectrum is various when it is tape-recorded at an atomic action of the surface area. Furthermore, the particular vibration modes can be observed selectively at the in your area oxidized website (figure 3), showing the atomic-scale chemical level of sensitivity of atomic-point-contact Raman spectroscopy.

It was formerly believed that a plasmonic nanogap is needed to get the ultrahigh level of sensitivity in tip-enhanced Raman spectroscopy, which usually needs a metal substrate. This enforced a serious restriction on quantifiable samples. The discovery of the huge Raman improvement upon the atomic point contact development will broaden the capacity of atomic-scale vibration spectroscopy, which applies to non-plasmonic samples and the extraordinary chemical level of sensitivity will be gotten for lots of other products. In addition, our outcomes likewise recommend that atomic scale structures play an important function in metal-semiconductor hybrid nanosystems to impact their optoelectronic residential or commercial properties.


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